The 4-4 exhausts are notorious for rotting out as they don't heat up like a 4-2 or 4-1, thus condensation, rust, etc. This particularly happens when you do a bunch of short hops, not allowing the pipes to come to full temp and evaporate the condensation. And yes, individual carb set-up can impact the exhaust temperature. Too lean and you'll run hot, cooking all sorts of stuff like your valves; that is in addition to the exhaust. My timing was off, and I noticed it when my 1-4 pipes were running noticeably colder than the 2-3 pipes. Of course, it was only running on 2 cylinders, so there were other obvious pointers that something was amiss.