The caliper piston seal divides the brake fluid from the atmosphere. The seal itself is lubed/preserved with Brake parts assembly lube. Any exposed metal on the caliper puck side of the seal (piston, caliper bore, brake puck backing) gets a thin coat of Dow High Vacuum grease.
I then make sure that a little additional grease fills the gap between brake puck steel backing and the caliper bore wall. This provides the barrier to keep dust and water from getting to bare metal behind the puck.
An assembly technique is to NOT push the caliper piston deep into the caliper on initial assembly. The piston/puck depth is set as you assemble onto the rotor. The helps keep the grease off the friction pads.
Cheers,