So when you say you cleaned it mate, you removed it from the carb, and looking thru it, you could see daylight, yeah? Then you blew the circuit out with compressed air, and you checked that it was totally unblocked too? Sorry if I sound like Lloyd, (Two Tired) but a lot of folks assume that they've cleaned everything when all they've really done is sprayed a bit of carb cleaner around?
If it's a valve problem, it'll most likely be a burned exhaust valve. Do you have a compression tester? If so, don't worry about firing the engine up to normal operating temperature, that is the best way, but if you do have a valve problem, even if the engine's cold, it'll still be obvious, as you'll have less than 100 psi pressure in that cylinder.
Check them all, and if you want to risk burning your pinkies on a hot header pipe run the engine by all means, (you'll never forget the pain, take it from me) but as I've explained above, not really necessary as the difference will be huge between a good cylinder and a bad one. I hope this helps! Cheers, Terry.