I took a class at the local community college to learn basic painting techniques. Was well worth the couple hundred dollars it cost.
I second the importance of prep work, our instructor ("Special" Ed Simmering) told us many times: "Clean, clean, clean, then when you are certain that it couldn't be any cleaner, clean it once more."
We did a class project (mine is in my ID photo) to prep, prime, paint, and clear coat a 2'x2' piece of steel. My kids helped me cut a blown-up Honda emblem out of a sheet of contact paper.
Holubs