You can stack button cells to achieve a 12.7V potential. But, they won't move a large enough quantity of electrons, to maintain that potential while providing current.
It is plate area that makes current. If the plates are eroded (reduced area), or covered in lead sulphate (insulation of area), there is a reduction in electrons available to flow.
You may observe that the 12.7V potential drops to a very low number when the battery is asked to deliver current. If a fully charged starting battery can't maintain 9-10V when the starter load (25-35 Amps) is placed upon it, it is usually worn out (plate loss) or sulphated (plate insulation) from neglect.
The electrolyte (turns to water), because the sulphur in battery acid H2SO4, deposits coat the plates with lead sulphate, leaving behind more H20.
A specific gravity test of the electrolyte will show sulphur loss due to conversion deposition (sulphation) or exhaustion (low state of charge).