TwoTired, what you're saying seems to makes sense... but then what I don't understand is why the "Aluminium safe" SG has a higher pH (10.9 per the MSDS), Sharpertek's carburetor cleaner has a pH of 10.4 at solution, and berryman's carb cleaner has a pH of 10-11.
I'm thinking there's more to this than the pH... maybe "aluminum safe" cleaners are adding something to prevent reactions with aluminum?
You are correct. Bear in mind I am not an expert in chemistry. I do know enough to be slightly dangerous.
I tried to keep the discussion simple. But, real answers can be complex.
As I understand it:
pH is a widely accepted term that refers to the Power of the Hydrogen ion in a chemical reaction. The hydrogen ion generally determines how fast a reaction takes place in the presence molecules that are able to combine. However, the presence of some chemicals can block or slow the reaction time. Or, if you chose just the right chemicals, there can't be a hydrogen ion exchange, as there are no places in the chemical composition available for transfer.
There is also the question of the test method or device used. If the standardized test material shows a pH indication, it may be because the test vehicle has the reactionary component whereas the actual subject material does not. In short, the reaction can take place with the test strip, but not when applied to the subject material. Further, MSDS pages are directed toward material handling and safety for humans. A chemical safely stored and transported in a conveyance container harmlessly may not be so harmless in free air, or in contact with skin, or contaminated with fire prevention chemicals.
Chemistry is an entire field of education, which has complexities rivaling advanced mathematical concepts, with similarly complex formulas.
The chemists that formulate the product, determine which application it is best suited. Simple Green makes a special composition variant which is safe for aluminum.
Pine sol doesn't make any such claims. In fact they specifically state: "
Do not use on marble, aluminum, copper or wood that is unfinished, unsealed, unpainted, waxed, oiled or worn."
The disclaimer is there for a reason. Not only does it absolve them of misuse of product, it also warns buyers about suitable applicability and shifts responsibility to the buyer/user of product.
All three of the following products are different because of their composition. Their applications also vary.
The MSDS of each product in the simple green line of offerings lists the chemicals within it:
Aluminum safe simple greenWater 7732-18-5 ≥ 78%
Triethanolamine 102-71-6 ≤ 10%
Ethoxylated Alcohol 68439-46-3 ≤ 5%
Propylene Glycol Butyl Ether 5131-66-8 ≤ 5%
Tetrapotassium Pyrophosphate 7320-34-5 ≤ 1%
Potassium Silicate
All purpose Simple greenWater 7732‐18‐5 ≥ 78%
2‐butoxyethanol 111‐76‐2 ≤ 5%
Ethoxylated Alcohol 68439‐46‐3 ≤ 5%
Tetrapotassium Pyrophosphate 7320‐34‐5 ≤ 5%
Sodium Citrate 68‐04‐2 ≤ 5%
Fragrance Proprietary Mixture ≤ 1%
Colorant
Compare to:
Pine sol Pine oil 3 - 7%
Alkyl alcohol ethoxylates 1 - 5%
Sodium petroleum sulfonate 1 - 5%
Glycolic acid 1 - 5%
Isopropyl alcohol