I am not certain about your header pipe being double walled. Should be able to determine that by measuring the thickness while it is removed. Applying pressure to a tube inside another tube, and predicting the distortion effects on the outer tube, seems a difficult task, indeed.
One of the physical properties of steel is that it "work hardens" when it is bent. To avoid work hardening, the metal is heated before or during the bending process. The dent in your pipe is now bent metal, and likely stretched a bit as well.
To restore this area without heat, you will need to apply point pressure in the opposite direction of the bend. If you use the entire pipe as a pressure vessel and increase the internal pressure to the point where the metal will distort, the distortion will likley first occur everywhere inside the pipe but where the metal has been hardened, i.e. your dent, and any other bends that occured since the metal was in a heated, plastic, state during the manufacture of the pipe.
If it were possible to remove the dent, and I suspect that it might be, how much is it worth to you? Lots of very difficult and complex tasks can be performed, given adequate resorces. Do you have a monetary value of the work you wish performed? Are you willing to risk the loss of your current pipe in experimental attempts? Is it worth making special tooling to remove the dent?
Might be cheaper to just fill in the dents and have it rechromed, though not nearly as adventurous.
Cheers,