Your float level could be too high, or your needle valve may be sticking open. Give the offending carb a couple of sharp taps with a screwdriver handle, sometimes that's enough to get the valve to seat properly and stop the overflow. Worth a try. You'll still need to deal with the petcock issue though, and if the screwdriver trick hasn't worked you'll need to check the float height and ensure there is no crud preventing the valve from seating.