With the advents in metallurgy through the decades, steel remains the preferred material. Lots f cast alloy frames in race bikes, but more CroMo it seems. If you look at cycling, Ti has had its binge, of course steel, and CroMo. Even Carbon Fiber has been popular at times. But repair, modification and general endurance of steel still prevails.
I like exotic materials. I love working with aluminum and am tinkering with some Ti. I marveled at Oakley's X Metal when they introduced it a year or two ago. "Purpose Beyond Reason"! You gotta love those who create despite market dynamics.
I'd like to see carbon wrapped tubing over an alloy core. Light, strong, and stiff. And possibly repairable. Just need a whole line of DIY-sized autoclaves to accompany those 3D Printers