Thanks guys. I have plenty of POR-15 left over from sealing the insides of the fork ears. I can easily clean, degrease, and coat the insides of these rims while I'm doing the rest of the work on them. Sounds like a much better solution than trying any of the coke/aluminum foil or baking soda /lemon juice approaches. The POR will prevent a reoccurrence of the same type of corrosion.
I guess that means I will have to remove the spokes to clean and paint the rim. Didn't want to get into that but looks like no other choice.