I would recommend more than some heat. Hit that thing with propane, penetrant and a hammer to shock it. You're not going to damage anything. The motor will act like a giant heat sink.
If heat and penetrant doesn't work I would weld a big nut on the threaded end and crank on it from that side. Once it breaks free just cut the bolt head off and slide it out.
This is the approach I'd take too, with a slight deviation. Instead of welding a nut onto the bolt, I'd use a TIG torch and attack the end of the rod from both sides. This will heat the rod only beyond propane, and dislodge and free up any rust making the bolt much, much easier to drive out. You can of course hit the rod with Kroil promptly after breaking the arc to help wick it deeper into the engine boss.
You WON'T hurt the motor, so allay your fears. The bolt will get super hot by 1,200* and that's not even close to breaking the oxide layer on the cases. If you were to use a thermal meter on the end of the bolt while you heated the bosses with propane, you'd see the cases (as Dave correctly stated) will suck the heat up. I'd be surprised if the bolt even got near 250* while the boss might see 400*. All these temps sound high, but in actuality they are not. And they are non-destructive to the strength or stability of these parts in question.
Acid on aluminum (anodized) is a bit tricky. All depends on the type of acid, the dilution, and whether its submerged or applied. Nevertheless, you have lots of options now, so do what you feel comfortable with. And if you get in a pickle over the bolt, let me know, I'll do what I can to help you with a replacement.