i'm certainly no expert, but as i've had it explained to me at my local metal plater, the finish before plating is very important, much like the prep process in painting. plating is very thin compared to powdercoating, and imperfections show very easily. i've been told the exact opposite---that most of what you pay for in chrome plating is in the preparation and polishing.
this from a chrome plating FAQ:
"The steps for tank plating of Chrome over steel, pot metal, zinc diecast or other metals is very similar to the tank plating of any common metal other then aluminum. Like any plating, most of the work is in the preparation. Preparation for plating is very similar to preparation for painting. The end results can only be as good as the finish on the piece before you start plating it. Sand, buff or polish the piece to get a good surface finish. Make sure you have removed all of the paint on the area that you want to plate."
i've been pricing having my new project frame plated instead of powdercoated, and i've been sent all over the place trying to find someone that will deal with it, due to complications in the process, such as adequate venting of any closed tubing that may trap hydrochloric acid during the cleaning process when the metal becomes particularly porous, which can cause serious corrosion problems from the inside out. there are powdercoats out there with metal flake in them, which can be clearcoated to give a metallic look.
in any case-- much like you, bryan, i want to make damn sure i have all welds finalized before doing anything permanent.