White smoke is almost certainly water vapor. Water is a byproduct of combustion, and the flow though of humidity in the air. Ignore it unless it persists for a half hour after the engine is at full operating temp while driving about.
Popping on decel is either a leaky exhaust or too lean an idle mixture setting, coupled with low exhaust back pressure for the mixture delivery.
You did put in new crush washers for the new exhaust, right? You did hang the rear of exhaust before tightening the header bolts, on the crush washers, right? Even new crush washers can be damaged/deformed upon installation.
Cheers,