With a new cam chain on my 650, I had the same problem.
step 1. make sure the tensioners lower end is in it's groove, you can verify by having the oil pan off and lying on the ground in my case and shining a torch up.
put chain on sprocket and lever it into position.
check alignment.
I don't know why but, that's the only way I managed. 20,000 KM's later every thing is still good.