Odd. I don't think the advancer can be 180 out, since it locates and drives with a pin on the advancer that goes into a hole in the crank end.
The cam itself can be put out of sync with the crank by engaging the chain on the sprocket incorrectly, but it can't be 180 degrees out as it turns at 1/2 crank degrees. You can be a sprocket tooth (or maybe two) out without crashing pistons and valves together.
I would confirm that it's at TDC 1-4 by eye or a straw to check that the 1-4 marks are in play. If not... well, that should not be possible.