First off, I'm making this up, but here's what I found. 2.0mm valves are for cb750k 69-75, however, the cmsnl photo for a 76 carb also shows a 2.0 needle seat. 2.5mm only shows a needle available, and the cb750's are much later years ( late 80's -early 90's) biggest visible difference is the rubber tip on the later ones
Simple answer...bigger needle valves flow more fuel.
There's a start.