Tubing (pipe) is normally notated by the ID size.
The wall thickness varies for every different application for a given pipe (hi PSI, low PSI, sewer or supply lines, etc.), so you'll often find tubing in sizes like 1/2", 1", 3", etc., but the OD designates the 'schedule' of the pipe. When I was in the oilfield, a "2 inch pipe" for 20,000 PSI was 5.8" (minimum) on the OD while a 2" fluid feeder pipe was 2.25" OD.
For the exhaust it will also be in mm sizes.
The header pipes are also split at the ends so they will slip over the exhaust spigot. Most have 2 splits, some have had 4 (early K1), but those tended to crack and break off.
Are you planning on making your own pipes? Many car muffler shops carry the benders and piping, often in 18-8 stainless steel.