Basic sprocket theory.
To gear lower (numerically higher)
- Smaller front sprocket
- Larger rear sprocket
- Both
To gear higher (numerically lower)
-Larger front sprocket
-Smaller rear sprocket
-Both.
If you go with that 36 tooth rear, you won't spin as many RPM's on the freeway, but you'll also lose some low end grunt. You may lose enough to make it a complete pain in the a$$ to ride in town, due to the relative lack of gear multiplication.
If it's fuel savings you're after, gearing the bike "up" that much may take the engine out of its comfortable powerband, and lugging it everywhere your fuel consumption may go up.
Also, keep in mind that you may lose some clearance in the engine cases when you gain too many teeth on the countershaft sprocket, and that chains don't really like to turn too tight of a radius when you drop teeth on that front.
There's more, but thats a very brief overview, and I hope it helps!