May I ask what keeps the colars "hooked" on to the pipe lips? Seem like (and I think mine are) they would want to slip off and get pushed into the gasket.
That's why you use tape or rubber bands to keep them there. The non flanged of the collars end gets pressed up
behind the trumpet like lip at the end of the exhaust pipe. The flanged end of the split collars, set in that groove of the cast iron collar. The cast iron collar pushes the split pieces up against the exhaust pipe trumpet end lip, which then goes up against the copper exhaust gasket and the head.
If you are reusing the split pieces, especially, where they may have become deformed somewhat, they will want to collapse in up against the pipe then then there is no pressure from the cast iron collar being transferred to the trumpet end of the exhaust pipe via the split collars, and thus leaks occur. Also, the non-flared ends of the split collars, can sometimes slip and go up and over the trumpet end of the exhaust pipe into the head area - again causing a leak.
What I ended up doing on one stubborn pipe, was construct two semi-circle shims out of aluminum, that fit between the split collars (towards the flanged end of the split collars) and the exhaust pipe, so that the whole assembly was "tapered" - bigger at the end that goes into the cast iron collar and smaller at the end that touches the copper gaskets. Then, I wrapped the assembly (split collars, shims, then exhaust pipe ends) with thin but strong rubber bands
(black silicone hair bands for doing corn rows, etc.. . .lol) to keep it all in place. The shims forced the split collars outward so they stayed up against the cast iron collars, upon tightening. I rode it up to temp for a bit, went home and then the shims were removed (so that everything heated and expanded correctly). I could have actually left the shims in but since they hung out a bit and were visible, I removed them - just yanked them out with pliers.
Here is a picture of the shims: (make as many sets of these as you need, use the rubber bands or tape trick, and those split collars HAVE to line up right if you are careful. Again though, I suggest you might want to buy a whole set of matching split collars, as mine were all identical and it looks like you have two different types, for some reason.