If I was an argumentative type, I'd remind the previous poster that 2 part urethane paints are relatively new, and laquer based paint was used from the 1920's to the 1990's with excellent "fuel resistant" properties, and are far less harmful to your health than 2 pack paints which contain some serious carcinogens, that will kill you dead, if you don't wear not only a good quality mask, but head to toe protection, as this stuff can also be absorbed into your skin. Also, 2 pack is a thick heavy bodied paint, and those little aerosol kits wouldn't have enough pressure (50 plus PSI) to adequately atomize it.
I don't know how good (or how safe) Rustoleum paint is, but unless it's an automotive paint, I'd recommend against it, unless you've seen some really good results with it. I've got a big compressor and every type of gun imaginable, but I've had really good results (like my June BOTM winning K2) with automotive laquer rattle cans. Don't heat anything more than room temps, it won't help, but it will hurt. Most paint needs to "flow out" and it can't do that if you're applying heat, especially with a (cringe) heat gun. Cheers, Terry.