i could be wrong, but... I think it's aluminum oxide. Is this film on the outside or the inside? It seems pretty common on the inside where minor aluminum pitting (blame long exposure to funky chemicals in gas) has lead to greater surface area, thus more space for a lot of oxide to build up. I got rid of some of it in my carb bowls by taking fine sandpaper to the surface, then a toothbrush with mother's polish. clean VERY well after with soap and hot water, dry well and use.