Glad you got it out with air.
One caution for those trying this, put your hand over the piston, maybe with a cloth, becuase the piston can come flying out at speed.
And since the topic will attract readers, I'll add what Kong alluded to. I had a piston that would not come out with air, 110psi. From a suggestion here, i did the grease gun method. Unthread/remove the tip from your grease gun hose. You'll have a male threaded end exposed. Thread it into the hose entry port of the caliper, with the other port closed off. Its not the same thread, so you'll only catch a few threads before it gives resistance and you should stop there to avoid damaging the caliper. Then pump the gun and to my surprise the piston came outsmoothly and easily, with about 5 pumps!
You'll have a caliper full of grease, but removal of the stuck piston is well worth it.