Thanks guys, always good advice here. The valve stems are not mushroomed, the motor has been sitting under a workbench for over 30 years and has some rust inside. I was able to push one valve out by hand and it looks ok except for the carbon deposits on the head of the valve. I was reluctant to go about my usual way of bashing things with a hammer for a change. It appears that a hammer is reasonable this time and changing the guides will most likely have to be done if the valves are going to be stubborn. Strangely the intake valves are all ok.
Cheers,
Cliff.