It's not possible to be certain of huge cause of the discoloration simply by looking at the head. It could be rich, it could be poor timing, it could be.... The exhaust valves often tend to look more "lean" due to the fact they are post-combustion. Did you happen to look at your plugs prior to disassembly? Was there a compression check? A leakdown test? If not, best to start taking micrometer measurements of the cylinders and pistons, ring gaps, clearances, etc. That way you know what condition your block is in and check the valves, guides and seals in the head.