These calipers I did as described - disassembled and cleaned with degreasers, then soda blasted, then masked, painted, cured, and baked, then rebuilt. That was...4 years ago? They still look perfect, have been bled and stray drops of brake fluid have landed on them - no problem.
These were painted with the specific VHT Brake Caliper paint that Eric refers to.
I went too heavy on at least one coat, accounting for a bit of the orange peel you see. If you go lighter and with more coats, you can avoid that, but in fact some of the Honda calipers look like this finish stock.
Before:
Stripped, cleaned, and soda blasted:
Masked and hung to paint:
Baking:
Painted, dried, pulling the tape:
Done: