What they've all said...
The "pads" are shoes which are not part of the hub/drum, they go with the backing plate. FYI: They haven't used asbestos for brake shoes in many years, though yours may be. Its nasty stuff.
I'd take out the bearings fo sho, they will likely bleed grease at least and may get ruined.
Ask the powder coater what they think about it. The drum part is steel and is pressed into the aluminum hub. Different coeficients of expansion, but at those temps probably OK. Warping the drum is possible, at some point.
No there is no rubber between the bearings.