I painted an assembled engine with Duplicolor Engine Enamel and let it air dry for two days. The nighttime temperature did not go below 70F when I did it. I painted the engine covers off the engine, baked them and then installed. I was very careful, I think, with cleaning the surfaces and letting them dry thoroughly before painting.
I don't notice much difference in the adhesion and durability of the paint I baked versus the paint I did not. On wear surfaces, like where my boot scuffs the tranny cover, the paint comes off, even though that was one of the surfaces that I baked.
Rattle can paint will never be as good as factory paint unfortunately.
Good luck with yours. Your mileage may vary.