As you go up in altitude you see less air density and the mix changes, so, yes octane plays a factor. The ethanol serves to increase the octane a little. But the burn rate slows as octane goes up, this is needed. It is not uncommon to have no pinging at lower altitudes only to see it appear in hot weather or at higher altitude.
Only solution is to increase the octane. You may have to run premium fuel and or make adjustment to the timing
I would not expect only a 1 point increase to have that much of an impact, but other changes may have contributed.