You might look at chapter 4 of the Honda CB500 550 shop manual. (download it from this site.)
If I recall correctly, a loose tensioner and the sprocket dismounted allows the chain to go on the sprocket.
Position the crank at T 1.4. Position the cam so the notch is facing forward, and then mount the cam sprocket on the cam.
If you are doing this without reference to the Honda shop manual. I expect failure in the long run, particularly when you put the cylinder cover on. You will bend valves and ruin the head's valve guides if you don't heed the warning in Figure 87. It is not simply a bolt it on affair, without meticulous alignment of the rocker tappets. Some use rubber bands to hold the rockers in position. I also back way out all the tappet adjusters.
Good luck!