Although I hesitate, I will respond. Forgive me if you know the following but by your question I think I'll throw it out there. Why have you decided to go to a big bore kit? Have you done what you can to improve the outside of the motor?
An engine is basically an air pump and the more air (mixed with fuel) you can get it to move, the more power it will make. Bigger pistons will move more air IF there is not a single restriction elsewhere in the air "channel". In theory, the air filter, carbs, valves, cams and exhaust are designed for how much air the 750's piston can move. Have you switch to a K&N type air filter? Are your carbs clean, properly jetted and tuned? Do you have a good aftermarket exhaust in place? Is your ignition system in top shape. Have you considered dyno tuning your bike? All these things are much cheaper than bigger pistons and potentially excellent power boosters. What's more all these things need to be in order to really see the maximum benefit from bigger pistons.
I'm new to the 750 engine. These are just general hot rod suggestions. The trick is to find where the biggest restriction in the air path is and open it up. Then find the next one, etc. I agree that head work has a lot of potential. It's labor intensive and manufacturers often skimp here, so that's a good bet.
Anybody know the biggest cork in the stock 750?